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What is it about?

1. four molecules make one unit in a crystal ; 2. the molecules are branchy in shape; 3. one molecule appear in neutral and anion form; 4. the neutral and anion form are indistinguishable from each other; 5. a chiral hydrogen-bonding synthon of R~5~^3^(10) was observed.

Why is it important?

1. rare. 1.1. just two cases are found. 1.2. multiple melocules appear in one crystal. another case: A hydrogen-bonded three-component complex: bis(dicyclohexylammonium) 2,4-dichlorophenolate 2,4,6-trichlorophenolate 2,4-dichlorophenol, Cai XQ, Jin ZM, ACTA CRYST C70, 207-209, 2014. 2. repetition: high or low? similar molecules used in these two case.

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Zhi-Min Jin
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